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PUBLICATIONS
(R: review articles, Ch: book chapter)

2012

51- Germylene and (Diazomethyl)germylene Complexes – Potential Precursors for a Transition-Metal–Germa-Alkyne Complex
E.  BONNEFILLE, N. SAFFON-MERCERON, C. COURET, S. MAZIERES
European Journal of Inorganic Chemistry, 35, 5771-5775, (2012)

50- Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization
P.E. DUFILS, G. DAVID, B. BOUTEVIN, G. WOODWARD, G. OTTER, A. GUINAUDEAU, S. MAZIERES, M. DESTARAC
Journal of polymer Science (part A), 50(10), 1997-2007 (2012)

R49- Well-defined macromolecular architectures through consecutive condensation and reversible-deactivation radical polymerizations
A. SANDEAU, S. MAZIERES, M. DESTARAC
Polymer, (53)25, 5601-5618 (2012)

48- Hybrid Polyion Complex Micelles Formed from Double Hydrophilic Block Copolymers and Multivalent Metal Ions: Size Control and Nanostructure
N. Sanson, F. Bouyer, M. Destarac, M. In, C. Gerardin,
Langmuir, 28(8), 3773-3782 (2012)

47- Direct Synthesis of Vinylidene Fluoride-Based Amphiphilic Diblock Copolymers by RAFT/MADIX Polymerization
E. Girard, J. D. Marty, B. Ameduri, M. Destarac
Acs Macro Letters , 1(2), 270-274 (2012)

46- Enhancement of Poly(vinyl ester) Solubility in Supercritical CO2 by Partial Fluorination: The Key Role of Polymer-Polymer Interactions
E. Girard, T. Tassaing, S. Camy, J. S. Condoret, J. D. Marty, M. Destarac
J. Am. Chem. Soc. , 134(29), 11920-11923 (2012)

45- Aqueous RAFT/MADIX polymerisation of N-vinyl pyrrolidone at ambient temperature
A. Guinaudeau, S. Mazieres, D. J. Wilson, M. Destarac,
Polym. Chem., 3, 81-84 (2012)

44- N-Heterocyclic carbene-catalysed synthesis of polyurethanes
O. Coutelier, M. El Ezzi, M. Destarac, F. Bonnette, T. Kato, A. Baceiredo, G. Sivasankarapillai, Y. Gnanou, D. Taton
Polym. Chem., 3, 605-608 (2012)

43- Aqueous RAFT/MADIX polymerisation of vinylphosphonic acid.
I. Blidi, R. Geagea, O. Coutelier, S. Mazieres, F. Violleau, M. Destarac
Polym. Chem., 3, 609-612 (2012)

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2011

42- Chromium and molybdenum pentacarbonyl complexes of phosphinocarbodithiotates: synthesis, molecular structure and behaviour in RAFT polymerisation.
R. GEAGEA, S. LADEIRA, S. MAZIERES, M. DESTARAC.
Chem. Eur. J., 17, 3718-3725 (2011)

41- Thermoresponsive poly(N-vinyl caprolactam)-coated gold nanoparticles: sharp reversible response and easy tunability.
M. BEIJA, J-D. MARTY, M. DESTARAC.
Chem. Comm., 47, 2826-2828. (2011)

40- Novel polyesteramide-based di-and triblock copolymers: from thermo-mechanical properties to hydrolytic degradation.
G. DESHAYES, C. DELCOURT, I. VERBRUGGEN, L. TROUILLET-FONTI, F. TOURAUD, E. FLEURY, P. DEGEE, M. DESTARAC, R. WILLEM, P. DUBOIS.
Eur. Polym. J., 47, 98-110 (2011)

39- Dixanthate-terminated poly(butylene terephthalate). A novel RAFT/MADIX agent for the synthesis of well-defined triblock copolymers resulting from consecutive step- and chain-growth polymerization processes
A. SANDEAU, S. MAZIERES, C. VERGELATI, C. CORRIOL, M. DESTARAC
Polym. Chem., 2, 2490-2499 (2011)

38- Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide
E. GIRARD, T. TASSAING, J.D. MARTY, M. DESTARAC
Polym. Chem., 2, 2222-2230 (2011)

R37- Chromium and molybdenum pentacarbonyl complexes of phosphinocarbodithioates : behavior in RAFT polymerization
S.MAZIERES, R. GEAGEA, M.DESTARAC
Polym. Prepr., (Am. Chem.Soc., Div. Polym. Chem.), 52(2), 544-545 (2011)

PR36- Aqueous RAFT/MADIX polymerization: same monomers, new polymers.
M. DESTARAC
Polym. Prepr., (Am. Chem.Soc., Div. Polym. Chem.), 52(2), 409-410 (2011)

PR35- Synthesis of Well-defined Triblock Copolymers Comprising a Poly(Butylene terephthalate) Midblock by the Combination of Step-growth and RAFT-MADIX Polymerizations 
A. SANDEAU, S. MAZIERES, C. VERGELATI, C. CORRIOL, M. DESTARAC
Polym. Prepr., (Am. Chem.Soc., Div. Polym. Chem.), 52(2), 673-674 (2011)

PR34- Room temperature aqueous RAFT/MADIX synthesis of thermoresponsive cationic diblock copolymers and their temperature-induced aggregation properties
E.READ, W.MOUSSA, J.D.MARTY, M.DESTARAC
Polym. Prepr., (Am. Chem.Soc., Div. Polym. Chem.),  52(2), 655-656 (2011)

PR33- Direct Aqueous RAFT/MADIX Polymerization of Vinylphosphonic Acid.
I.BLIDI, R. GEAGEA, O. COUTELIER, F. VIOLLEAU, M. DESTARAC
Polym. Prepr., (Am. Chem.Soc., Div. Polym. Chem.),  52(2) 636-637 (2011)

PR32-N-Heterocyclic Carbene-catalyzed synthesis of Polyurethanes
O. COUTELIER, M. EL EZZI, M. DESTARAC, F. BONNETTE, T. KATOI, A. BACEIREDO, G. SIVASANKARAPILLAR, Y. GNANOU, D. TATON
Polym. Prepr., (Am. Chem.Soc., Div. Polym. Chem.),  52(2)290-291 (2011)

PR31- Structure-solubility in sc-CO2 relationships of poly(vinyl acetate)-based (co)polymers synthesized by RAFT/MADIX polymerization
E. GIRARD, T. TASSAING, J.D. MARTY, M. DESTARAC
Polym. Prepr., (American Chemical Society, Division of Polymer Chemistry), 52(2), 661-662 (2011)

R30- On the critical role of RAFT agent design in reversible addition-fragmentation (RAFT) polymerization.
M. DESTARAC.
Polym. Rev., 51 (2), 163-187 (2011)

R29- RAFT/MADIX polymers for the preparation of polymer-inorganic nanohybrids.
M. BEIJA, J-D. MARTY, M. DESTARAC.
Prog. Polym. Sci., 36 (7), 845-886 (2011)

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2010

28- Thermoresponsive amphiphilic diblock copolymers synthesized by MADIX/RAFT: properties in aqueous solutions and use for the preparation and stabilization of gold nanoparticles
S. SISTACH, M. BEIJA, V. RAHAL, A. BRULET, J-D.MARTY, M. DESTARAC, C. MINGOTAUD.
Chem. Mater., 22, 3712–3724 (2010)

27- Control of the catalytical properties and directed assembly on surfaces of MADIX/RAFT polymer-coated gold nanoparticles by tuning polymeric shell charge.
M. BEIJA, E. PALLEAU, S. SISTACH, X. ZHAO, L. RESSIER, C. MINGOTAUD, M. DESTARAC, J-D. MARTY.
J. Mater. Chem., 20, 9433–9442 (2010)

26- Controlled radical polymerization: industrial stakes, obstacles and achievements.
M. DESTARAC
Macromol. React. Eng., 4, 165–179 (2010)

25- Aqueous MADIX/RAFT polymerization of diallyldimethylammonium chloride: extension to the synthesis of poly(DADMAC)-based double hydrophilic block copolymers.
M. DESTARAC, A. GUINAUDEAU, R. GEAGEA, S. MAZIERES,1 E. VAN GRAMBEREN, C. BOUTIN, S. CHADEL, J. WILSON.
J. Polym. Sci.: Part A: Polym. Chem., 48, 5163–5171 (2010)

24- Thermoresponsive poly(N-Vinyl Caprolactam)-coated gold nanoparticles: sharp response and easy tunability.
M. BEIJA, J-D. MARTY, M. DESTARAC.
Chem. Commun. 2010, DOI: 10.1039/c0cc05184e.

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2009

23 - Hybrid block copolymers incorporating oligosaccharides and synthetic blocks grown by controlled radical polymerization.
J. Lohmann, C. Houga, H. Driguez, J. Wilson, M. Destarac, S. Fort, J-F. Le Meins, R. Borsali, D. Taton, Y. Gnanou.
ACS Symposium Series, 2009, 1023 (Controlled/Living Radical Polymerization: Progress in ATRP), 231-240

22 - A comprehensive investigation into “controlled/Living” chain growth crosslinking copolymerization including a back to basics modeling
J. Poly, D. Taton, J. Wilson, M. Destarac.
J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 5313-5327

21 - MADIX thermoresponsive amphiphilic block copolymers as stimulable emulsion stabilizers.
M. Destarac, A. Papon, E. Van Gramberen, K. Karagianni.
Aust. J. Chem.2009, 62, 1488-1491

22 - Novel Polyesteramide-Based Diblock Copolymers: Synthesis by Ring-Opening Copolymerization and Characterization
G. DESHAYES, C. Delcourt, I. Verbruggen, L. Trouillet-Fonti, F. Touraud, E. Fleury, P. Degée, M. Destarac, R. Willem, P. Dubois.
Macromol. Chem. Phys., 2009, 210(12), 1033-1043

19 - Reactivity of a germa-alkyne: Evidence for a germanone intermediate in the hydrolysis and alcoholysis processes.
E. BONNEFILLE, S. MAZIERES, N. SAFFON, C. COURET
J. Organomet. Chem. 2009, 694, 2246-2251

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2008

Ch18 - Macromolecular Design by Interchange of Xanthates (MADIX): Background, Design, Scope, and Applications.
D. TATON, M. DESTARAC, S.Z. ZARD.
Handbook of RAFT Polymerization, C. Barner-Kowollik, Ed.; Wiley-VCH:Weinheim 2008, 373-421.

17 - Synthesis of poly(vinyl acetate) nanogels by xanthate-mediated radical crosslinking copolymerization.
J. POLY, D.J. WILSON, M. DESTARAC, D. TATON.
Macromol. Rapid. Commun. 2008, 29, 1965-1972.

16 - First cationic borohydrido-neodymium complex: Synthesis, characterization and its application as efficient pre-catalyst for isoprene polymerization.
M. VISSEAUX, M. MAINIL,M. TERRIER,A. MORTREUX,P. ROUSSEL,T. MATHIVET,, M. DESTARAC.
J. Chem. Soc., Dalton Trans. 2008, 4558-4561.

15 - Activation of the hydrolytic polymerization of e-caprolactam by ester functions: straightforward route to aliphatic polyesteramides.
G. DESHAYES, C. DELCOURT, I. VERBRUGGEN, L. TROUILLET-FONTI, F. TOURAUD, E.FLEURY, P. DEGEE, M. DESTARAC, R. WILLEM, P. DUBOIS.
React. Funct. Polym. 2008, 68, 1392-1407.

14 - Harnessing the Potential of N-Heterocyclic Carbenes for the Rejuvenation of Group-Transfer Polymerization of (Meth)Acrylics.
J. RAYNAUD, A. CIOLINO, A. BACEIREDO, M. DESTARAC, F. BONNETTE, T. KATO, Y. GNANOU, D. TATON.
Angew. Chem. Int. Ed. 2008, 47, 5390-5393.

13 - A process for polymerizing vinyl phosphonic acid with C6F13I perfluoroalkyl iodide chain-transfer agent.
G. DAVID, C. BOYER, R. TAYOUO, S. SEABROOK, B. AMEDURI, B. BOUTEVIN, G. WOODWARD, M. DESTARAC.
Macromol. Chem. Phys. 2008, 209, 75-83.

12 - A Synthetic Equivalent of a Germanone Derivative.
E. BONNEFILLE, S. MAZIERES, C. BIBAL, N. SAFFON, H. GORNITZKA, C. COURET
Eur. J. Inorg Chem 2008, 4242–4247

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2007

11 - Encapsulated N-Heterocyclic Carbenes in silicones without reactivity modification.
F. BONNETTE, T. KATO, M. DESTARAC, G. MIGNANI, F.P. COSSIO, A. BACEIREDO.
Angew. Chem. Int. Ed. 2007, 46, 8632-8635.

10 - Radical telomerisation of vinyl phosphonic acid with a series of chain transfer agents.
G. DAVID, B. BOUTEVIN, S. SEABROOK, M. DESTARAC, G. WOODWARD, G. OTTER.
Macromol. Chem. Phys. 2007, 208, 635-642.

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2006

9 - Water soluble polymeric nanogels by xanthate-mediated radical crosslinking polymerisation.
D. TATON, J-F. BAUSSARD, L. DUPAYAGE, J. POLY, Y. GNANOU, V. PONSINET, M. DESTARAC, C. MIGNAUD, C. PITOIS.
Chem. Commun. 2006, 18, 1953-1955.

8 - Hydrophilic block copolymer-directed growth of lanthanum hydroxide nanoparticles.
F. BOUYER, N. SANSON, M. DESTARAC, C. GERARDIN.
New J. Chem. 2006,30, 399-408.

7 - Vinylogous thionothio compounds for RAFT Polymerization.
M. DESTARAC, I. GAUTHIER-GILLAIZEAU, C-T. VUONG, S. Z. ZARD.
Macromolecules 2006, 39, 912-914.

6 - Synthesis and chemistry of aryloxygermylene-amine complexes.
E. BONNEFILLE, S. MAZIERES, N. EL HAWI, H. GORNITZKA, C. COURET
J. Organomet. Chem. 2006,691, 5631-5637

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2005

5 - A “living” radical ab initio emulsion polymerization of styrene using a fluorinated transfer agent.
M. MONTEIRO, M. ADAMY, B.J. LEEUWEN, A.M. VAN HERK, M. DESTARAC.
Macromolecules 2005, 38, 1538-1541.

4 - MADIX polymerization of captodative ethyl a-acetoxyacrylate with acrylate monomers.
D. BATT-COUTROT, J-J.ROBIN, W. BZDUCHA, M. DESTARAC.
Macromol. Chem. and Phys. 2005, 206, 1709-1717.

3 - Electrophoretic behavior of amphiphilic diblock copolymer micelles.
A. MOREL, H. COTTET, M. IN, S. DEROO, M. DESTARAC.
Macromolecules 2005, 38, 6620-6628.

2 - Radio frequency film characterization with polymer-coated Love-wave sensor.
F. RAZAN, C. ZIMMERMANN, D. REBIERE, C. DEJOUS, J. PISTRE, M. DESTARAC, B. PAVAGEAU.
Sensors and Actuators B, 2005, B108 (1-2), 917-924.

1 - Reactivity of Germene Mes2Ge:CR2 with Cumulative Unsaturation-Containing Compounds: Synthesis of New Germanium Heterocycles.
S. E-C. EL KETTANI, M. LAZRAQ, H. RANAIVONJATOVO, J. ESCUDIE, C. COURET, H. GORNITZKA, A. ATMANI.
Organometallics 2005, 24, 5364-5368.

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Patents (P)

2012

P25 - Controlled free radical polymerization of N-vinyl lactams in an aqueous medium. Rhodia Opérations/CNRS
M. DESTARAC, A. GUINAUDEAU, S. MAZIERES,.
WO12045944.

P24 - Preparation of hydrophilic polymers of high molar mass by controlled radical polymerization. Rhodia Opérations/CNRS
M. DESTARAC, A. GUINAUDEAU, S. MAZIERES, J. WILSON
WO12042167.

2010

Rhodia Opérations
G. CRINIERE, M. DESTARAC, C. PITOIS
EP 2219774.

P22 - Manufacture of inorganic-organic composite particles by formation of an inorganic material within a polymer. Rhodia Opérations
M. DESTARAC, C. PITOIS.
FR 2934505

P21 - Heat-sensitive emulsions comprising amphiphilic block copolymers. Rhodia Opérations.
K. KARAGIANNI, M. DESTARAC.
WO 2010010124

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2009

P20 - Hybrid compounds containing polysaccharide(s) and at least one polyoxyalkylene, method for preparing same, and applications thereof.
E. FLEURY, M. TIZZOTTI, M. DESTARAC, M-P. LABEAU, T. HAMAIDE, E. DROCKENMULLER.
WO 2009063082, 22-05-2009

P19 - Ampholytic copolymer with controlled architecture-Rhodia Opérations.
M. DESTARAC.
WO 2009059887, 14-06-2009

P18 - Opening of epoxy cycles by carbenes-Rhodia Opérations / CNRS.
M. DESTARAC, G. MIGNANI, A. BACEIREDO, D. TATON, Y. GNANOU, J. RAYNAUD.
WO 2009013344, 29-01-2009

P17 - Synthesis of urethanes and polyurethanes catalyzed by carbenes- Rhodia Opérations / CNRS.
G. MIGNANI, M. DESTARAC, D.TATON, Y. GNANOU, A. BACEIREDO, T. KATO, F. BONNETTE, G. SIVASANKARAPILLAI.
WO 2009016322, 05-02-2009

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2008

P16 - Polymeric microgel comprising cationic units- Rhodia Opérations.
I. GONZALEZ, D. J. WILSON, M. DESTARAC, K. KARAGIANNI.
WO 2008155282, 24-12-2008

P15 - Process for modification of dithiocarbonyl group-containing polymers by contact with amine groups supported by a solid substrate- Rhodia Opérations.
M. DESTARAC.
Fr 2916448, 28-11-2008

P14 - Composition comprising a carbene and an organic matrix, production method thereof and use thereof- Rhodia Opérations
M. DESTARAC, G. MIGNANI, A. BACEIREDO, T. KATO, F. BONNETTE.
WO 2008068258, 12-06-2008

P13 - Controlled polymerization of monomers bearing an alpha,beta-unsaturated group in the presence of a carbene- Rhodia Opérations
A.BACEIREDO, F. BONNETTE, M. DESTARAC, R. DEVASIA, Y. GNANOU, T. KATO, D. TATON.
WO 2008068348, 12-06-2008

P12 - Polymerization catalyst system containing active borohydride- Rhodia Opérations
M. DESTARAC, T. MATHIVET, M. MAINIL, A. MORTREUX, M. VISSEAUX.
FR 2906534, 04-04-2008

P11 - Block copolymer, process for making the same, and use in emulsions- Rhodia Opérations
S. DEROO, W. BZDUCHA, S. TOUZET, M. DESTARAC.
WO2008019984, 21-02-2008

P10 - Polymerization from a diallylamine and a compound containing a macromolecular chain deriving from such an amine- Rhodia Chimie
M. DESTARAC
WO 2008000766, 03-01-2008

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2007

P9 - Manufacture of telomers and controlled-architecture copolymers of vinylphosphonic compounds using iodine-transfer polymerization- Rhodia Chimie.
M. DESTARAC, B. BOUTEVIN, G. DAVID, G. OTTER, G. WOODWARD.
WO 2007085623, 02-08-2007

P8 - Organosols stabilized by amphiphilic polymers-Rhodia Chimie
M. DESTARAC
WO 2007077357, 12-07-2007

P7 - Compounds with terminal xanthate and silane groups and their use in polymer transformation- Rhodia Chimie
M. DESTARAC, S.Z.ZARD, F. RIVALS, I. QUICLET-SIRE, G. MIGNANI.
Fr 2889702, 16-02-2007

P6 - Mineral particles with surfaces modified by compounds with xanthate and silane groups as materials reactive with polymers- Rhodia Chimie
M. DESTARAC, C. MIGNAUD
Fr  2889704, 16-02-2007

P5 - Block copolymer comprising a block having a lower critical solution temperature, formulations comprising the copolymer and use thereof for vectorizing active substances- Rhodia Chimie
M. DESTARAC, B. BAVOUZET
WO 2007012763, 01-02-2007

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2006

P4 - Copolymer of controlled architecture derived from vinyl phosphonate monomers, method for preparing same and uses thereof-Rhodia Chimie
M. DESTARAC
WO 2006/125892, 30-11-2006

P3 - Organosols stabilized by amphiphilic block copolymers-Rhodia Chimie
M. DESTARAC, B. PAVAGEAU, B. TOLLA
WO 2006117476, 09-11-2006

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2005

P2 - Synthèse de copolymères en forme d’étoile mikto par polymérisation radicalaire contrôlée-Rhodia Chimie
C. PITOIS, M. DESTARAC, D. TATON
WO 2005116097, 08-12-2005

P1 - Polymers containing isocyanate groups obtained from (co)polymers containing groups having labile hydrogen, their preparation, and their use in coating compositions-Rhodia Chimie
J-M. BERNARD, M. DESTARAC, C. VARRON-DUFFY
WO 2005100428, 27-10-2005

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